Manganese oxides in Martian meteorites Northwest Africa (NWA) 7034 and 7533

نویسندگان

چکیده

We report the discovery of indigenous Mn-oxides in Martian regolith breccias Northwest Africa (NWA) 7034 and 7533. These occur Mn-rich regions as nanocrystals mixed with silicates, FeOOH, possible phosphates. The contain up to 34 wt% Mn typically display large chemical gradients on scale 10–20 μm. origin was established by presence glass (4.8–5.6 Mn) fusion crust that crosscuts a Mn-oxides-bearing monzonite clast absence environmentally exposed surfaces (exterior fractures) meteorites. Manganese K-edge X-ray absorption spectrum (XAS) indicated this included high-valent species. Synchrotron micro-X-ray diffraction region basalt XAS three clasts indicate these are dominantly hollandite-structured 67–85 mol% total being Mn4+. fact present diverse petrological associations but absent matrix indicates formed through surface alteration prior final brecciation event assembled NWA Thus, age is older than lithification (arguably 1.35 Ga) Together findings phases within Noachian Hesperian sedimentary strata Endeavour Gale craters, our results suggest common weathering product Mars, suggesting aqueous environment high redox potential.

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ژورنال

عنوان ژورنال: Icarus

سال: 2021

ISSN: ['0019-1035', '1090-2643']

DOI: https://doi.org/10.1016/j.icarus.2021.114471